Permalink Settings control to network admin

Hi,

You have two plugins which gives us option to hide Permalink Settings for every site on the network...

I'm using the Ultimate branding plugin, and have enabled the Permalink Settings to be removed.

Now the setting is been removed on each site on the network.
Where Can I Go TO Change / apply a universal Permalink Settings to all sites on the network?

Other Question>
You can please suggest a plugin to optimize the Database /and remove post revision (something similar to wp-optimize).
A plugin that can be managed through the network, not each site.
Hope you got what I mean.

Lastly I have been thinking of building an IOS app.
My question is > I am a windows user, Can I make the IOS App using your WP for IOS.

Thanks.